Silicones for Personal Care, 2nd Edition

Author::

Anthony O'Lenick, Jr.

Format::

Hardcover

$189.00

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Format Details

Hardcover
417 Pages
Published 2008
ISBN-10: 1-932633-36-7
ISBN-13: 978-1-932633-36-8

For customers in Austria, Germany, Poland and Switzerland, please place your order through our distributor, Wissenschaftliche Verlagsgesellschaft (WVG)

Description
Table of Contents
Author Information
Expert Reviews

Silicone polymers have become increasingly important in advanced cosmetic formulations through the years. Silicone science is an area seeing many new developments being made, any of which could revolutionize the industry. Do you know everything you should?

Silicones for Personal Care, 2nd Edition provides invaluable information to the cosmetic chemist about the basic chemistry and properties of these important silicones. This book stresses the various steps in the synthesis of silicone compounds—construction, functionalization and derivitization—which have a profound impact on performance. Topics include:

Basic silicone materials
Emulsions
Silicone surfactants
Silicone esters
Silicone complexes
Silicone resins

Preface
About the Author/Acknowledgement
1. Introduction
- Silicone
- Comparing Silicon with Carbon
- Silicone Compounds
- Silicone from Quartz
- Rochow Process—Chlorosilanes from Silicon
- Hydrolyzate—Silicone from Chlorosilanes
- Reactions of Chlorosilanes
- Silicones Properties
- Silicone Backbone Nomenclature
2. Basic Silicone Materials
- Cyclomethicone
- Molecular Weight of Polymeric Silicones
- Silicone Fluids
- Silicone on Substrate
- Cosmetic Usage of Silicone Fluids
- Silanol Compounds
3. Silicone Antifoam Compounds
- Mechanism of Antifoam
- Testing Antifoam Performance
4. Emulsion
- Emulsion Terminology
- Emulsion Stability
- Silicone Emulsions
- Types of Emulsions
- Deposition of Naturally Derived Hair Color via Reactive
- Silicone Emulsions
5. Silicone Surfactants
- Silicone Molecule Preparation
- Equilibration
- Derivitization
6. Dimethicone Copolyol Chemistry
- Reaction
- Dimethicone Copolyol Properties
- Structure Function Study
- Water Solubility
- Water Tolerance
- Odor
- Hydroxypropyl Dimethicone
7. Silicone Esters
- Reaction
- Properties
- Solubility Properties
- Triglyceride-Derived Dimethicone Copolyol Esters
- Dimethicone Copolyol Meadowfoamate
- Meadowfoam Silicone
- Ester Structure/Function
- Other Esterification Methods
8. Alkyl Dimethicone Copolyol Compounds
- Orientation at the Interface
- Emulsification Properties
- 3D Partition Coefficient
9. Fluoro Dimethicone
- Surface Tension Reduction
- Chemistry
- Low Fluoro Compounds
- High Fluoro Compounds
- Fluoro Alkyl Silicones
10. Alkyl Dimethicone
- Typical Physical Properties
- Alkyl Dimethicone Orientation on Surfaces
- Structure/Function Properties
- Alteration of Functionalization
- Melt Point
- Alteration of Construction
- Physical Properties
- Alteration of Properties
- SPF Enhancement
11. Cationic Silicone Compounds
- Silanol Groups
- Amino Groups
- D Units
- Dimethicone Copolyol Amine
- Polymerization Process
- Applications Evaluation
12. Carboxy Silicone Complexes
- Energetics of Complex Formation
- Mild Conditioning Products
- Fatty Quaternary Ammonium Compounds
- Chemistry
- Desirable Properties of Cationic Silicone Complexes
- Silicone/Silicone Complexes
13. Silicone Phosphate Esters
- Emulsifiers
- Water Soluble Emollients
- Foaming Agents
- Irritation Reduction of Sodium Lauryl Sulfate
- Irritation Reduction of Alpha Hydroxy Acids (AHA)
14. Silicone Resins
- Chemistry
- Applications
- Future Developments
15. Silicone Phospholipids
- Phosphobetaines
- Phospholipids
- Complexation with Anionic Surfactants
- Silicone Products
- Chemistry
16. HLB
- HLB System
- Applicability of the HLB System to Surfactant Types
- Three-Dimensional HLB
- Testing the 3-D HLB System
17. Applying the Three-Dimensional HLB System
- The 3-D HLB System
- Compounds
- Testing
- Discussion
- Emulsifier Kits
18. Silicone Quats
- Structure
- Properties
- Softness
19. Silicone Ester Amido Quaternary Compounds
- Formulating
- Applications Data—Foam
- Wet Comb Test
20. Silicones for Coating Pigments
- Definitions
- Historical Perspective
- Silicone Coatings for Pigments
- Pigment Reactive Binding Mechanisms
- Silicone Structure
- Chemistry
- Other Functional Groups
21. Silicone Surface Tension in Formulation
- Silicone in Mixed Systems
- Simple Surfactant Systems
- Test Methodology
22. Properties of Silicone Compounds
- Refractive Index
- Surface Tension
- Foam
23. Reactive Silicone Compounds
24. Methods in Silicone Chemistry
- Instrumental Methods
- Wetting Test Methodology
- Additional Silicone Information
- Optimization of Emulsion
25. Future Trends
- Technology
Appendix A
Index

Anthony J. O'Lenick, Jr. has more than 30 years of experience in innovative personal care ingredients. He is president of Siltech LLC, a company he founded in 1989, specializing in functional silicones and specialty surfactants. O'Lenick has five published books, more than 40 technical articles and is the inventor of more than 260 patents.

Other books published by this author/editor:

“[Silicones for Personal Care, 2nd Edition] highlights the various steps on the synthesis of silicone compounds construction, functionalization and derivitization, giving the possibility to the reader to understand their performances and activities on the human body and the environment…”

Read the full review from the Journal of Applied Cosmetology.

—P. Morganti
Editor in Chief
Journal of Applied Cosmetology

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